Galactomannans - Viscosity and gelation

4 important questions on Galactomannans - Viscosity and gelation

What can decrease the viscosity of galactomannans?

When galactomannans would be heated at rather low pH values, the viscosity will drop with decreasing Mw.

Do galactomannans give a good viscosity?

Yes, they have a high water-binding capacity forming highly viscous solutions at low concentrations.

How do galactomannan and xanthan interact?

  1. Non-substituted parts of locust bean gum (so no galactosyl residues) interacts via cations(+) with the helical xanthan structure
  2. Backbone of galactomannan can interact with xanthan despite being substituted.
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Why is the degree of substitution important for the interaction between galactomannan and other polysaccharides?

Guar gum (2:1) + xanthan gum --> increase in viscosity
Guar gum (2:1) + gelling polysaccharide (agar, carrageenan) --> gel strength increased

Locust bean gum (4:1) + xanthan gum --> gelling agent, while both are not gelling agents when used alone, but only increase the viscosity

Tara gum (3:1) + xanthan gum --> gel, but weaker compared to LBG

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