Ice cream - Effect of emulsifiers and stabilizers

12 important questions on Ice cream - Effect of emulsifiers and stabilizers

Which emulsifiers are often added to ice cream?

Polysorbate 80 and lecithin (eggs).

What happens when casein proteins cover the fat particles? And how can this be solved?

The coalescence of fat particles is decreased, which results in less stable air bubbles. The case proteins can be replace by polysorbate 80 or lecithin molecules as they are better fat emulsifiers.

Why are polysorbate 80 and lecithin better emulsifiers than casein proteins?

They are smaller, the fat particles can come closer together, and have better possibility to coalesce.
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How do stabilisers (polysaccharides) control the amount of ice formed?

Stabilisers have hydroxyl groups with which they can form hydrogen bonds. They are able to absorb and bind water. This will decrease the amount of free water. Since only free water is able to freeze, the decrease in free water will decrease the amount of ice.

What is the difference in the release of fat and water soluble flavours?

Water soluble flavours are present in the matrix and are released rapidly on consumption. Fat soluble flavours are release more slowly.

Which 3 ingredients of milk and cream influence the properties of ice cream and what is their size?

  1. Milk fat globules (1 um) --> partly solid and partly liquid (dependent on temperature)
  2. Whey proteins (5 nm) --> globular
  3. Casein micelles (100-300 um) --> assembly of casein molecules

Why does fat only partially coalesce?

Because fat globules are partly liquid and partly solid. The surfaces will overlap but due to the solid character, they do not merge any further.

Why and how can casein micelles on the fat globules be removed?

They stabilise the fat globules, but you want the fat globules to coalesce.
To remove the caseins, you can replace the casein micelles by other surface active agents (such as polysorbate 80). The surface active agents are amphiphilic and have a higher affinity to the fat globules than the casein micelles. The surfactants are smaller and the fat globules can now approach each other much easier, can coalesce and stabilise the air bubbles.

What happens when surfactants are added in ice cream with a low fat content?

There is a competition between casein micelles, whey proteins and the surfactants. The surfactants outcompete the proteins and sit on the interface. When there are too many surfactants present, the air bubbles approach each other. The surfactants are small, which makes the interface not thick enough. This leads to coalescence of the air bubbles, not favourable for ice cream as it can collapse.

Do surfactants stabilize or destabilise the ice cream?

Both!

  • Stabilize --> removing casein micelles from fat globules (destabilising them). Fat globules can coalesce and sit on the interface of the air bubbles, making them stable.
  • Destabilize --> outcompete casein micelles and whey proteins on the interface of the air bubbles. They give a thin interface due to their small size and this gives coalescence and destabilisation of the air bubbles.

What is the percentage of stabiliser in the beginning of the freezing process and in the end?

0.5% at the beginning
As 60-70% of water solidifies: the serum concentration increases with a factor 3
So from 0.5 to 1.5% polysaccharide solution

What are functions of stabilisers?

  • Water-binding ability --> free water decrease: less ice
  • Create smoothness in texture and eating --> viscosity increase, limit ice crystal growth
  • Reduction of meltdown
  • Slowing down moisture migration
  • Masking detection of ice crystals
  • Incorporation of air

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