Ideal vapor-liquid equilibrium
7 important questions on Ideal vapor-liquid equilibrium
When can a solution be considered ideal?
- A strongly dilutes solution. For example salt in water.
Considering a closed, ideal, system with species A and B, constant P and T, what variables contribute to the equilibrium condition of the system?
Because all interactions: A-A=A-B=B-B, there is no change in H.
Only the entropy S remains.
Explain the variables in the Boltzman entropy:
is the sum of all possible configurations of molecules in a grid.
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For a two component ideal mixture, how can the Bolzman entropy be calculated?
The sum of configurations is calculated as follows:
How can the Gibbs free energy for an ideal solution be calculated?
How is the chemical potential of one component in an ideal solution derived?
on the phase line :
Taking the partial derivative of G:
How is the chemical potential of component i in an ideal gas mixture expressed?
where y is the molar fraction of gas.
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