Kinetic data and their interpretation - Interpretation of rate constants - Transition state theory
5 important questions on Kinetic data and their interpretation - Interpretation of rate constants - Transition state theory
When can the transition state theory be applied?
The transition state theory can only be applied when all individual reaction steps of a process are known.
What is the rate of product formation proportional to?
It is proportional to the concentration of X‡. v= k‡[X‡] = k‡K‡[A][B].
What are the Eyring equations?
k = ((T kb)/h)exp(-dG‡/RT)
k = ((T kb)/h) exp(-dH‡/RT)exp(dS‡/R)
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What is a measure for the amount of binding energy that is lost in the formation?
The enthalpy of activation dH‡.
What does the entropy of activation dS‡ signifies?
It signifies the amount of order of the activated complex relative to the starting point.
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